Abstract: In the situation of \rho-mixing dependent sequences, this paper studied the mean square error and the optimal bandwidth of distribution kernel estimator nu_p,h of VaR. And the optimal bandwidth minimized the mean square error. The density function of Laplace distribution is used in the calculation of bandwidth and we adopt the method of interpolation to compute specific value of bandwidth in this paper. According to the numerical simulations, the distribution kernel estimator is more accurate by comparing the performance of VaR distribution kernel estimation with a common order statistic. Finally, Shangzheng A-share index and Shenzheng B-share index are chosen for an empirical research, which concludes that the risk of the latter is significantly higher than that of the former.